I-iron complex desulfurization inezici zomthamo omkhulu wokumuncwa kwesibabule, ukusebenza kahle kwe-desulfurization ephezulu, isivinini esisheshayo sokukhishwa kwesibabule kanye nokuvuselelwa kwe-oxidation, ukubuyiswa kalula kwesibabule, i-desulfurizer engangcolisi, futhi itholakale ekusetshenzisweni kwezimboni.
Inqubo ye-iron complex desulfurization ingafinyelela ku-99.9% H2Izinga lokususwa kwe-S emikhakheni eminingi yezimboni, okuhlanganisa nokukhipha igesi yemvelo, isizinda sikawoyela ongahluziwe, ukuhluzwa kwe-petroleum, ukwelashwa kwegesi yebhayoloji, igesi yesulfure yamakhemikhali negesi ye-coke oven, njll.
Kulezi zinqubo zezimboni, umthamo wegesi okufanele uphathwe kusuka kuma-cubic metres ambalwa kuya ezinkulungwaneni zama-cubic metres, kanye nesibabule esikhiqizwa nsuku zonke sisuka kumakhilogremu ambalwa kuya emashumini amathani.
I-H2Okuqukethwe kwe-S kwegesi ephathwa uhlelo lwensimbi oluyinkimbinkimbi kungaphansi kwe-1PPmV.
Isici
(1) Izinga lokususwa kwe-hydrogen sulfide liphezulu, isilinganiso sokuqala sokususwa kwesinyathelo sokusabela singaphezu kuka-99.99%, kanye nokugcwala kwe-H2I-S kugesi yomsila elashiwe ingaphansi kuka-1 ppm.
(2) Ibanga elibanzi lesicelo, lingabhekana nezinhlobonhlobo ze-H2S igesi.
(3) Umsebenzi uyavumelana nezimo futhi ungavumelana nokuguquguquka okukhulu kwe-H2S ukugxila kanye nezinga lokugeleza kwegesi eluhlaza ukusuka ku-0 kuye ku-100%.
(4) Ayinandaba nemvelo, akukho mfucuza emithathu ekhiqizwayo.
(5) Izimo zokusabela ezithambile, isigaba se-liquid kanye nenqubo evamile yokusabela kokushisa.
(6) Inqubo elula, ukugijima kwezitshalo / ukumisa nokusebenza kwansuku zonke kulula.
(7) Ukusebenza kwezomnotho okuphezulu, unyawo oluncane, izindleko zokutshala izimali ezincane kanye nezindleko zokusebenza zansuku zonke eziphansi.
(8) Ukusebenza okuphezulu kokuphepha, uhlelo alusebenzisi noma yimaphi amakhemikhali anobuthi futhi imikhiqizo yesibabule ayinayo i-H2S igesi.
Inkambu yohlelo lokusebenza
Igesi yemvelo kanye ne-gas desulfurization ehambisanayo
I-Acid tail gas desulfurization kanye nokubuyiswa kwesibabule
I-refinery gas desulfurization
I-coke oven gas desulfurization
I-Biogas desulfurization
I-Syngas desulfurization
I-1, i-desulfurization yensimbi evamile
Lapho usebenzisana negesi evuthayo noma enye igesi ewusizo, umbhoshongo ozimele wokumuncwa kanye nombhoshongo we-oxidation uyamukelwa futhi i-iron complex catalyst impompa emkhunjini ngepompo ye-booster.I-absorber ihlukanisa i-H2S isuka kugesi equkethe isibabule futhi iyiguqulela ku-elemental sulphur.Ikholomu ye-oxidation ingabuyisa i-iron complex catalyst.I-desulfurization kanye nokuvuselelwa kwenziwa ngokulandelana emibhoshongweni emibili, ngakho-ke kubizwa ngokuthi inqubo yemibhoshongo emibili.
2, I-self-circulating iron desulfurization eyinkimbinkimbi
Inqubo yokuzijikeleza ingasetshenziswa lapho usebenzisana namagesi e-amine namanye amagesi aphansi angashi.Kulolu hlelo, umbhoshongo wokumunca kanye nombhoshongo we-oxidation kuhlanganiswe ibe yiyunithi eyodwa, ngaleyo ndlela kuncishiswe umkhumbi owodwa, futhi kuqedwe iphampu yokujikeleza kwesixazululo kanye namadivayisi ahlobene namapayipi.
I-oxidation yesibabule
H2Inqubo yokumuncwa kanye nenqubo ye-Ionization - Inqubo Yokudlulisa Okuningi - Isinyathelo sokulawula isilinganiso
H2I-S+ H2O HS-+ H+
Inqubo ye-Sulfur oxidation - Ukusabela okusheshayo
HS-+ 2Fe3+ S°(izi) + H++ 2Fe2+
Isibabule sakhiwe njengesiqinile futhi sakha i-iron bivalent engasebenzi
Inqubo yokuvuselela i-Catalyst
Inqubo yokumuncwa komoya-mpilo - inqubo yokudluliswa kwenqwaba, isinyathelo sokulawula izinga, umthombo womoya-mpilo umoya
Ukuvuselelwa kwe-Catalyst - Inqubo yokusabela esheshayo
½ O2+ 2Fe2++ H2O2Fe3++ 2OHH-