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I-Methanol Cracking Hydrogen Production Plant

  • Okuphakelayo okujwayelekile: I-Methanol
  • Ibanga lamandla: 10~50000Nm3/h
  • H2ubumsulwa: Imvamisa 99.999% ngevol. (ongakukhetha 99.9999% ngevolumu.)
  • H2ukucindezela kokuhlinzeka: Imvamisa amabha ayi-15 (g)
  • Ukusebenza: Okuzenzakalelayo, i-PLC ilawulwa
  • Izinsiza: Okokukhiqiza okungu-1,000 Nm³/h H2kusuka ku-methanol, Izinsiza ezilandelayo ziyadingeka:
  • 500 kg/h methanol
  • 320 kg/h amanzi ancibilikisiwe
  • Amandla kagesi angu-110 kW
  • 21T/h amanzi okupholisa

Isingeniso Somkhiqizo

Inqubo

Ividiyo

I-Methanol Cracking Hydrogen Production Technology isebenzisa i-methanol namanzi njengezinto zokusetshenziswa, iguqule i-methanol ibe igesi exutshwe nge-catalyst futhi ihlanze i-hydrogen ngokusebenzisa i-pressure swing adsorption (PSA) ngaphansi kwezinga lokushisa elithile nokucindezela.

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Izici Zobuchwepheshe

1. Ukuhlanganiswa okuphezulu: idivayisi enkulu ngaphansi kuka-2000Nm3/h kungenziwa kweqiwa futhi kunikezwe iyonke.

2. Ukuhlukahluka kwezindlela zokushisa: ukushisa kwe-oxidation catalytic; Ukushisa kwegesi ye-self-heating flue; Ukushisa kwamafutha okushisa kwesithando somlilo; Ukushisisa kukagesi okwenziwa ngowoyela wokushisa.

3. Ukusetshenziswa kwe-methanol okuphansi: ukusetshenziswa okuncane kwe-methanol okungu-1Nm3I-hydrogen iqinisekisiwe ukuthi ingaphansi kuka-0.5kg. Ukusebenza kwangempela ngu-0.495kg.

4. Ukubuyiselwa kwesigaba samandla okushisa: khulisa ukusetshenziswa kwamandla okushisa futhi unciphise ukunikezwa kokushisa ngo-2%;

(1) Ukuqhekeka kweMethanol

Hlanganisa i-methanol namanzi ngesilinganiso esithile, ukucindezela, ukushisa, ukuhwamuka bese ushisa ngokweqile ingxube ukuze ifinyelele izinga lokushisa elithile kanye nokucindezela, khona-ke phambi kwe-catalyst, ukusabela kokuqhekeka kwe-methanol kanye ne-CO shifting reaction yenza ngesikhathi esifanayo, futhi ukhiqize ingxube yegesi ne-H2, CO2kanye nenani elincane le-CO eyinsalela.

Ukuqhekeka kwe-Methanol kuwukusabela okuyinkimbinkimbi kwe-multicomponent enegesi eminingana kanye nokusabela kwamakhemikhali aqinile

Ukusabela okukhulu:

CH3OHjtCO + 2H2- 90.7kJ/mol

CO + H2OjtCO2+ H2+ 41.2kJ/mol

Ukusabela okufingqiwe:

CH3OH + H2OjtCO2+ 3H2- 49.5kJ/mol

 

Yonke le nqubo iyinqubo ye-endothermic. Ukushisa okudingekayo kokusabela kunikezwa ngokujikeleza kwamafutha okuqhuba ukushisa.

Ukonga amandla okushisa, igesi eyingxube ekhiqizwe ku-reactor yenza ukushintshaniswa kokushisa noketshezi oluxubile olubalulekile, bese iyajiya, bese igezwa embhoshongweni wokuhlanza. Uketshezi oluxubile olusuka ku-condensation kanye nenqubo yokugeza luhlukaniswa embhoshongweni wokuhlanza. Ukwakheka kwalolu ketshezi oluxubile ikakhulukazi amanzi ne-methanol. Ibuyiselwa ethangini lempahla eluhlaza ukuze igaywe kabusha. Igesi yokuqhekeka efanelekayo ibe isithunyelwa ophikweni lwe-PSA.

(2) I-PSA-H2

I-Pressure Swing Adsorption (PSA) isekelwe ekukhangiseni ngokomzimba kwama-molecule egesi endaweni engaphakathi ye-adsorbent ethile (izinto eziqinile ezinezimbobo). I-adsorbent kulula ukukhangisa izingxenye ezibilisa kakhulu futhi kunzima ukukhangisa izingxenye ezibilisa kancane ngengcindezi efanayo. Inani le-adsorption likhuphuka ngaphansi kwengcindezi ephezulu futhi lehla ngaphansi kwengcindezi ephansi. Lapho igesi yokuphakelayo idlula kumbhede we-adsorption ngaphansi kwengcindezi ethile, ukungcola okubilayo kuyakhangiswa ngokukhetha futhi i-hydrogen ebilisa kancane engakhangisiwe kalula iyaphuma. Ukuhlukaniswa kwe-hydrogen nezingxenye zokungcola kuyabonakala.

Ngemuva kwenqubo ye-adsorption, i-adsorbent idonsa ukungcola okumuncwayo lapho inciphisa ukucindezela ukuze ikwazi ukuvuselelwa ukuze i-adsorb futhi ihlukanise ukungcola futhi.